New routes to the preparation of [ru3(co)12], [h4ru4(co)12], [rucl2(pph3)3] and [rucl2(cod)]n from anglo platinum refinery

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Date

2013

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Zimbabwe Journal of Science and Technology

Abstract

New and improved routes for the preparation of ruthenium complexes are described. [Ru3(CO)12], [H4Ru4(CO)12], [RuCl2(PPh3)3] and [RuCl2(COD)]n have been prepared from [(NH4)2RuCl6] and [H2RuCl6]. Traditionally these ruthenium complexes have been prepared from commercially available RuCl3.3H2O, but here we describe their preparation from refinery materials.

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Journal Article

Keywords

Ruthenium complexes, Ruthenium trichloride trihydrate, Refinery materials, Ammonium hexachlororuthenate, Dihydrogen hexachlororuthenate

Citation

Chiririwa, H. & Moss, J.R., 2013. New Routes to The Preparation of [ Ru 3 ( CO ) 12 ], [ H 4 Ru 4 ( CO ) 12 ], Materials. Zimbabwe Journal of Science and Technology, 8, pp.1–8.

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http://ir.nust.ac.zw:4000/handle/123456789/406

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Applied Chemistry Publications

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